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References

2013

Articles:

Devolder, T., Tahmasebi, T., Eimer, S., Hauet, T. and Andrieu, S.
Applied Physics Letters, 103(24)
2013

Equipe: Département P2M : Nanomagnétisme et Electronique de Spin

Hamdan, A., Noel, C., Kosior, F., Henrion, G. and Belmonte., T.
Journal of the Acoustical Society fo America, 134:991
2013

Resume: The determination of the initial pressure at the bubble wall created by a discharge in heptane for micro-gap conditions cannot be determined straightforwardly by modeling the time-oscillations of the bubble. The resolution of the Gilmore equation gives the same solutions beyond 1 mu s typically for various sets of initial parameters, making impossible the determination of the initial pressure at the bubble wall. Furthermore, the very first instant of the bubble formation is not easily accessible at very short time scales because of the plasma emission. Since the pressure waves propagate in the liquid, it is much easier to gain information on the first instants of the bubble formation by studying the pressure field far from the emission source. Then, it is possible to deduce by modeling what happened at the beginning of the emission of the pressure waves. The proposed solution consists in looking at the oscillations affecting another bubble located at least twice farther from the interelectrode gap than the maximum radius reached by the discharge bubble. The initial plasma pressure can be determined by this method. (C) 2013 Acoustical Society of America.

Equipe: Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS

Hamdan, A., Noel, C., Kosior, F., Henrion, G. and Belmonte, T.
JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 134(2, 1):991-1000 Belmonte, T (Reprint Author), Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, Parc Saurupt,CS 14234, F-54042 Nancy, France. Hamdan, A.; Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, F-54042 Nancy, France.
2013
ISSN: 0001-4966

Resume: The determination of the initial pressure at the bubble wall created by a discharge in heptane for micro-gap conditions cannot be determined straightforwardly by modeling the time-oscillations of the bubble. The resolution of the Gilmore equation gives the same solutions beyond 1 mu s typically for various sets of initial parameters, making impossible the determination of the initial pressure at the bubble wall. Furthermore, the very first instant of the bubble formation is not easily accessible at very short time scales because of the plasma emission. Since the pressure waves propagate in the liquid, it is much easier to gain information on the first instants of the bubble formation by studying the pressure field far from the emission source. Then, it is possible to deduce by modeling what happened at the beginning of the emission of the pressure waves. The proposed solution consists in looking at the oscillations affecting another bubble located at least twice farther from the interelectrode gap than the maximum radius reached by the discharge bubble. The initial plasma pressure can be determined by this method. (C) 2013 Acoustical Society of America.

Equipe: Centre de Compétences : ERMIONE informatique et calcul

Zhang, H.Y., Cleymand, F., Noel, C., Kahn, C.J.F., Linder, M., Dahoun, A., Henrion, G. and Arab-Tehrany, E.
Carbohydrate Polymers, 93(2):401-411
2013

Resume: This work addresses the functionalization of chitosan thin films and its nanoliposomes blend films by a microwave-excited Ar/N2/H2 surface-wave plasma treatment which was found an effective tool to modify surface properties. Changes in the film properties (wettability, chemical composition, morphology) induced by the plasma treatment are studied using water contact angle measurements, X-ray photoelectron spectroscopy and scanning probe microscopy. The results suggest that hydrophilicity of the films is improved by plasma treatment in a plasma condition dependency manner. Water contact angle of chitosan films before and after plasma treatment are, respectively, 101° and 27°. Besides chemical changes on the surface, the nanoliposomes incorporation and plasma treatment also induce morphological modifications. Moreover, a correlation is found between the nanoliposomes composition and size, and the effects of plasma treatment. It is shown that the plasma treatment significantly improves the chitosan film functionalization. The effect of N2 content (88% and 100%) in the plasma gas mixture on the film etching is also pointed out.

Equipe: Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS

Chichti, E., Henrion, G., Cleymand, F., Jamshidian., M., Linder, M. and Arab Tehrany, E.
Plasma Processes and Polymers, 10:535-543
2013

Resume: Poly-lactic acid (PLA) is the most used biopolymer in both biomedical and food packaging fields to replace petrochemical plastics. The surface properties of PLA thin films were studied before and after plasma treatment to enhance its wettability and its adhesive properties. Based on the experimental design, the most significant parameters of the plasma process were specified. The effect of the cold plasma treatment on the mechanical, topographic composition, thermal and barrier properties of the PLA was carried out using different Ar-N2-O2 gas mixture. Results show that the discharge gas can have a significant influence on the chemical composition and the wettability of the PLA surfaces. As the plasma processing is a surface treatment without affecting the bulk properties, it did not change the PLA properties.

Equipe: Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS

Martin, J., Melhem, A., Shchedrina, I., Duchanoy, T., Nominé, A., Henrion, G., Czerwiec, T. and Belmonte, T.
Surface and Coatings Technology, 221:70
2013

Resume: The plasma electrolytic oxidation (PEO) of aluminium alloys is investigated for different electrical working conditions using a pulsed bipolar current supply. A particular attention is paid to the effect of the anodic current density (from 10 to 90 A dm-2) and current pulse frequency (from 100 to 900 Hz) on the resulting oxide layer. Micro-discharges are characterized during the process by means of fast video imaging with a time and a space resolution of 8 μs and 0.017 mm2, respectively. Correlations are established between themicro-discharge characteristics (surface density, lifetime and size) and the elaborated oxide layers (morphology, growth rate and surface roughness). The highest coating growth rate measured (2.1 μm min-1) is achieved with the combination of the highest current density (75.7 A dm-2) and the highest current pulse frequency (900 Hz). Within these specific current conditions it is concluded that the detrimental effects of numerous micro-discharges are minimized. The results also show that the surface roughness may be largely affected by the presence of long-lived and large micro-discharges which develop over the processed surface. The strongest micro-discharges (live duration up to 0.3 ms and cross-sectional area up to 1 mm2) are mainly observed with the combination of the highest current density (75.7 A dm-2) and the lowest current pulse frequency (100 Hz).

Equipe: Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS

Riahi, H., Montaigne, F., Rougemaille, N., Canals, B., Lacour, D. and Hehn, M.
Journal of Physics Condensed Matter, 25(29)
2013

Equipe: Département P2M : Nanomagnétisme et Electronique de Spin

Melchior, P., Rollinger, M., Thielen, P., Alebrand, S., Bierbrauer, U., Schneider, C., Gottwald, M., Hehn, M., Mangin, S., Cinchetti, M. and Aeschlimann, M.
Physical Review B - Condensed Matter and Materials Physics, 88(10)
2013

Equipe: Département P2M : Nanomagnétisme et Electronique de Spin

Tung, W-S., A. Daoud, W. and Henrion, G.
Thin Solid Films, 545:310-319
2013

Resume: A microwave-generated plasma afterglow (MWGPA) treatment was applied to keratin fibers to improve their adhesion to anatase nanocrystals by modifying their surface chemical and physical structure. The induced photocatalytic self-cleaning property has significantly been improved by 70% as evidenced by complete stain decomposition in 6 h only. The effects of gas mixtures, gas flow, treatment distance, treatment duration and power flow of the MWGPA treatment on keratin's surface were investigated. The MWGPA-induced alteration of keratin's surface structure resulted in an increase in the uptake of anatase crystals and thus enhanced photocatalytic self-cleaning activities. The contact angle, absorption time, deposition behavior, adhesion and stability of anatase coating of keratin fibers are discussed. The anatase uptake and coating uniformity were characterized quantitatively using Time-of-Flight Secondary Ion Mass Spectrometry. This efficient and low energy plasma surface activation approach demonstrated potential toward the practical application of anatase in keratinous materials.

Equipe: Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS

Riahi, H., Montaigne, F., Rougemaille, N., Canals, B., Lacour, D. and Hehn, M.
Journal of Physics Condensed Matter, 25(33)
2013

Equipe: Département P2M : Nanomagnétisme et Electronique de Spin

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