This file was created by the TYPO3 extension bib --- Timezone: CET Creation date: 2021-01-25 Creation time: 01-11-36 --- Number of references 71 article 201-3792 3D Trajectories Construction of Controlled Tungsten Melting Droplet in ASDEX Upgrade Journal of Nuclear Materials 2013 438 S846-S851 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.jnucmat.2013.01.183 Z.Yang K.Krieger T.Lunt F.Brochard J-L.Briançon R.Neu R.Dux A.Janzer S.Potzel T.Pütterich TheAsdex Upgrade Team article 201-3775 A study of helium atmospheric-pressure guided streamers for potential biological applications Plasma Sources Science and Technology 2013 22 025020 The origin of differences in the rotational temperatures of various molecules and ions (N-2(+)(B), OH(A) and N-2(C)) is studied in helium atmospheric-pressure guided streamers. The rotational temperature of N-2(+)(B) is room temperature. It is estimated from the emission band of the first negative system at 391.4 nm, and it is governed by the temperature of N-2(X) in the surrounding air. N-2(X) is ionized by direct electron impact in the outer part of the plasma. N-2(+)(B) is deactivated by collisions with N-2 and O-2. The rotational temperature of OH(A), estimated from the OH band at 306.4 nm, is slightly higher than that of N-2(+)(B). OH(A) is excited by electron impact with H2O during the first 100 ns of the applied voltage pulse. Next, OH(A) is produced by electron impact with OH(X) created by the quenching of OH(A) by N-2 and O-2. H2O diffuses deeper than N-2 into the plasma ring and the rotational temperature of OH(A) is slightly higher than that of N-2(+)(B). The rotational temperature of N-2(C), estimated from the emission of the second positive system at 315.9 nm, is governed by its collisions with helium. The gas temperature of helium at the beginning of the pulse is predicted to be several hundred kelvin higher than room temperature. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1088/0963-0252/22/2/025020 K.Gazeli C.Noel F.Clement C.Daugé P.Svarnas T.Belmonte article ISI:000312635200016 A wide-bandgap metal-semiconductor-metal nanostructure made entirely from graphene NATURE PHYSICS 2013 9 1 49-54 Département P2M : Surfaces et Spectroscopies 1745-2473 10.1038/NPHYS2487 J.Hicks A.Tejeda A.Taleb-Ibrahimi M. S.Nevius F.Wang K.Shepperd J.Palmer F.Bertran P.Le Fèvre J.Kunc W. A.de Heer C.Berger E. H.Conrad article 201-3771 Agglomeration processes sustained by dust density waves in Ar/C2H2 plasma: from C2H2 injection to the formation of an organized structure. Physics of Plasmas 2013 20 033703 In this paper, an experimental investigation of dust particle agglomeration in a capacitively coupled RF discharge is reported. Carbonaceous particles are produced in an argon plasma using acetylene. As soon as the particle density becomes sufficient, dust density waves (DDWs) are spontaneously excited within the cathode sheath. Recently, it was proven that DDWs can significantly enhance the agglomeration rate between particles by transferring them a significant kinetic energy. Thus, it helps them to overcome Coulomb repulsion. The influence of this mechanism is studied from acetylene injection to the formation of very large agglomerates forming an organized structure after a few dozens of seconds. For this purpose, three diagnostic tools are used: extinction measurements to probe nanometer-sized particles, fast imaging for large agglomerates and a dust extraction technique developed for ex-situ analysis. (C) 2013 American Institute of Physics. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1063/1.4796047 S.Dap R.Hugon D.Lacroix L.de Poucques J.-L.Briançon J.Bougdira. article Blampain20134607 AlN/sapphire: Promising structure for high temperature and high frequency saw devices IEEE Sensors Journal 2013 13 12 4607-4612 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84885609754&partnerID=40&md5=e7de8c1a0f7b023bfb0703ada6976506 E.Blampain O.Elmazria T.Aubert B.M.Assouar O.Legrani article ISI:000317163800001 Application of sputtered ruthenium nitride thin films as electrode material for energy-storage devices SCRIPTA MATERIALIA 2013 68 659-662 Centre de Compétences : X-Gamma rayons X et spectroscopie 1359-6462 10.1016/j.scriptamat.2013.01.030 S.Bouhtiyya R. LucioPorto B.Laik P.Boulet F.Capon J. P.Pereira-Ramos T.Brousse J. F.Pierson article ISI:000315834800005 Arc Behaviour and Cathode Melting Process during VAR: an Experimental and Numerical Study ISIJ INTERNATIONAL 2013 53 2 213-220 The present study aims to understand the melting of the consumable electrode in the VAR process and gain some insight into the influence of an ensemble arc motion on the melting behaviour. In a previous study, a 2D axisymmetric model of the heat transfer in the cathode had been developed. Using the operating parameters as model inputs, it enabled prediction of the melt rate and the evolution of the melting area. Model results were successfully compared to melt rate measurements in an industrial VAR furnace. In recent years, it has been claimed that the electric arc may not be considered as steady and axisymmetric. Our experimental investigation of the luminosity recorded during an actual VAR heat confirms that a transient 3D behaviour may take place. Therefore, a 3D version of the previous model was set up to predict the heat transfer and melting of the electrode, using the unknown ensemble arc motion as an input. The arc is assimilated to a transient distribution of energy flux density. Results evidence that the influence of the arc motion on the shape of the electrode tip can be very important. In industrial practice, the cathode tip usually remains relatively flat during melting. The shapes of the computed electrode tips enable us to propose some arc parameters which remain compatible with both the periodic behaviour of the light emitted and the flatness of the electrode. Centre de Compétences : ERMIONE informatique et calcul 0915-1559 10.2355/isijinternational.53.213 AlainJardy PierreChapelle AshishMalik Jean-PierreBellot HerveCombeau BernardDussoubs article 201-3773 Argon ion and neutral metastable levels destruction in a magnetically enhanced inductively coupled plasma reactor. The Open Plasma Physics Journal 2013 6 32-43 This paper deals with pure argon plasma studied in a magnetically enhanced inductively coupled reactor. Laser induced fluorescence technique was performed with an optical parametric oscillator laser on the 3d4F7/2 and 3d2G9/2 Ar+ metastable levels and on the (2P03/2)4s2 neutral metastable state to determine their relative densities. Langmuir probe was used as a complementary diagnostic to measure the electron energy distribution functions. When increasing the confinement magnetic field, the metastable state density collapses for all cited levels, by contrast with ne which is continuously growing. Calculations were carried out for neutral argon to explain this behaviour. The results show that the metastable population is depleted by electron-impact excitation and ionization, these loss processes becoming dominant compared to the metastable state creation term. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.2174/1876534301306010032 T.Bieber X.Glad LDe Poucques R.Hugon J.-L.Vasseur J.Bougdira. article Kalitsov2013 Bias dependence of tunneling magnetoresistance in magnetic tunnel junctions with asymmetric barriers Journal of Physics Condensed Matter 2013 25 49 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84887750963&partnerID=40&md5=5dedcb741c1f5d830deccd7e86a3e979 A.Kalitsov P.-J.Zermatten F.Bonell G.Gaudin S.Andrieu C.Tiusan M.Chshiev J.P.Velev article ISI:000324827200023 Cation size effect on the thermochromic properties of rare earth cobaltites RECoO3 (RE: La, Nd, Sm) JOURNAL OF APPLIED PHYSICS 2013 114 Centre de Compétences : X-Gamma rayons X et spectroscopie 0021-8979 10.1063/1.4821884 F.Capon A.BOILEAU C.Carteret N.Martin P.Boulet J. F.Pierson article ISI:000322738900034 Dynamics of bubbles created by plasma in heptane for micro-gap conditions JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA 2013 134 2, 1 991-1000 The determination of the initial pressure at the bubble wall created by a discharge in heptane for micro-gap conditions cannot be determined straightforwardly by modeling the time-oscillations of the bubble. The resolution of the Gilmore equation gives the same solutions beyond 1 mu s typically for various sets of initial parameters, making impossible the determination of the initial pressure at the bubble wall. Furthermore, the very first instant of the bubble formation is not easily accessible at very short time scales because of the plasma emission. Since the pressure waves propagate in the liquid, it is much easier to gain information on the first instants of the bubble formation by studying the pressure field far from the emission source. Then, it is possible to deduce by modeling what happened at the beginning of the emission of the pressure waves. The proposed solution consists in looking at the oscillations affecting another bubble located at least twice farther from the interelectrode gap than the maximum radius reached by the discharge bubble. The initial plasma pressure can be determined by this method. (C) 2013 Acoustical Society of America. Belmonte, T (Reprint Author), Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, Parc Saurupt,CS 14234, F-54042 Nancy, France. Hamdan, A.; Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, F-54042 Nancy, France. Centre de Compétences : ERMIONE informatique et calcul ACOUSTICAL SOC AMER AMER INST PHYSICS
STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA
Article English 0001-4966 10.1121/1.4812255 A.Hamdan C.Noel F.Kosior G.Henrion T.Belmonte
article 201-3776 Dynamics of bubbles created by plasma in heptane for micro-gap conditions Journal of the Acoustical Society fo America 2013 134 991 The determination of the initial pressure at the bubble wall created by a discharge in heptane for micro-gap conditions cannot be determined straightforwardly by modeling the time-oscillations of the bubble. The resolution of the Gilmore equation gives the same solutions beyond 1 mu s typically for various sets of initial parameters, making impossible the determination of the initial pressure at the bubble wall. Furthermore, the very first instant of the bubble formation is not easily accessible at very short time scales because of the plasma emission. Since the pressure waves propagate in the liquid, it is much easier to gain information on the first instants of the bubble formation by studying the pressure field far from the emission source. Then, it is possible to deduce by modeling what happened at the beginning of the emission of the pressure waves. The proposed solution consists in looking at the oscillations affecting another bubble located at least twice farther from the interelectrode gap than the maximum radius reached by the discharge bubble. The initial plasma pressure can be determined by this method. (C) 2013 Acoustical Society of America. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1121/1.4812255 A.Hamdan C.Noel F.Kosior G.Henrion T.Belmonte. article ISI:000325342500026 Effect of deposition conditions on the stoichiometry and structural properties of LiNbO3 thin films deposited by MOCVD 2013 8626 Centre de Compétences : X-Gamma rayons X et spectroscopie Teherani, FH and Look, DC and Rogers, DJ 0277-786X 10.1117/12.2010105 SamuelMargueron AusrineBartasyte ValentinaPlausinaitiene AdulfasAbrutis PascalBoulet VirgaudasKubilius ZitaSaltyte article 201-3774 Effects of electrical parameters on the plasma electrolytic oxidation of aluminium Surface and Coatings Technology 2013 221 70 The plasma electrolytic oxidation (PEO) of aluminium alloys is investigated for different electrical working conditions using a pulsed bipolar current supply. A particular attention is paid to the effect of the anodic current density (from 10 to 90 A dm-2) and current pulse frequency (from 100 to 900 Hz) on the resulting oxide layer. Micro-discharges are characterized during the process by means of fast video imaging with a time and a space resolution of 8 μs and 0.017 mm2, respectively. Correlations are established between themicro-discharge characteristics (surface density, lifetime and size) and the elaborated oxide layers (morphology, growth rate and surface roughness). The highest coating growth rate measured (2.1 μm min-1) is achieved with the combination of the highest current density (75.7 A dm-2) and the highest current pulse frequency (900 Hz). Within these specific current conditions it is concluded that the detrimental effects of numerous micro-discharges are minimized. The results also show that the surface roughness may be largely affected by the presence of long-lived and large micro-discharges which develop over the processed surface. The strongest micro-discharges (live duration up to 0.3 ms and cross-sectional area up to 1 mm2) are mainly observed with the combination of the highest current density (75.7 A dm-2) and the lowest current pulse frequency (100 Hz). Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.surfcoat.2013.01.029 J.Martin A.Melhem I.Shchedrina T.Duchanoy A.Nominé G.Henrion T.Czerwiec T.Belmonte article Leroy2013 Electronic structure of the Cr(001) surface and Cr/MgO interface Physical Review B - Condensed Matter and Materials Physics 2013 88 20 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84890478492&amp;partnerID=40&amp;md5=33bd021e302100970ac45c3c8e9b4e0c M.-A.Leroy A.M.Bataille F.Bertran P.Le Fèvre A.Taleb-Ibrahimi S.Andrieu article Melchior2013 Energy-resolved magnetic domain imaging in TbCo alloys by valence band photoemission magnetic circular dichroism Physical Review B - Condensed Matter and Materials Physics 2013 88 10 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84884866863&amp;partnerID=40&amp;md5=2a0167f587bb7ba10893fc9a287dca61 P.Melchior M.Rollinger P.Thielen S.Alebrand U.Bierbrauer C.Schneider M.Gottwald M.Hehn S.Mangin M.Cinchetti M.Aeschlimann article 201-3791 ESTELL: a quasi-Toroidally Symmetric Stellarator Contributions to Plasma Physics 2013 53 459-468 This work presents the physics design for a simple quasi-axially symmetric stellarator. A plasma configuration described by a modest number of Fourier coefficients was found to establish this symmetry with good accuracy. The low rotational transform results in a relatively simple coil set exhibiting low curvatures and comfortable clearance between adjacent coils. As another consequence, the maximum achievable plasma pressure will be limited to about 0.5%. An experiment along the lines proposed would allow an exploration of the confinement properties of a quasi-axially symmetric configuration. ((c) 2013 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim) Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1002/ctpp.201200055 M.Drevlak F.Brochard P.Helander J.Kisslinger M.Mikhailov C.Nührenberg J.Nührenberg Y.Turkin article ISI:000321430200020 First-order Raman scattering of the MAX phases: Ti2AlN, Ti2AlC0.5N0.5, Ti2AlC, (Ti0.5V0.5)(2)AlC, V2AlC, Ti3AlC2, and Ti3GeC2 (vol 43, pg 168, 2012) JOURNAL OF RAMAN SPECTROSCOPY 2013 44 7 1060 Département P2M : Surfaces et Spectroscopies 0377-0486 10.1002/jrs.4325 VolkerPresser MichaelNaguib LaurentChaput AtsushiTogi GillesHug Michel W.Barsoum article Nguyen20132039 Flexible over-moded resonators based on P(VDF-TrFE) thin films with very high temperature coefficient IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control 2013 60 10 2039-2043 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84884731426&amp;partnerID=40&amp;md5=e4b15f6fd6d6ca6cf26601b027cae853 V.S.Nguyen L.Badie E.Sénéchault E.Blampain B.Vincent C.Venet O.Elmazria D.Rouxel article BenYoussef2013309 Functional poly(urethane-imide)s containing Lewis bases for SO2 detection by Love surface acoustic wave gas micro-sensors Sensors and Actuators, B: Chemical 2013 185 309-320 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84878604866&amp;partnerID=40&amp;md5=5522f6482b5aeb9fa0d4f0fead3cdf3d I.Ben Youssef H.Alem F.Sarry O.Elmazria R.Jimenez Rioboo C.Arnal-Hérault A.Jonquières article ISI:000331751200002 Geometrically frustrated magnetism of spins on icosahedral clusters: The Gd3Au13Sn4 quasicrystalline approximant PHYSICAL REVIEW B 2013 88 21 Département CP2S : Métallurgie et Surfaces 1098-0121 10.1103/PhysRevB.88.214202 P.Kozelj S.Jazbec S.Vrtnik A.Jelen J.Dolinsek M.Jagodic Z.Jaglicic P.Boulet M. C.de Weerd J.Ledieu J. M.Dubois V.Fournee article ISI:000331751200002 Geometrically frustrated magnetism of spins on icosahedral clusters: The Gd3Au13Sn4 quasicrystalline approximant PHYSICAL REVIEW B 2013 88 Centre de Compétences : X-Gamma rayons X et spectroscopie 1098-0121 10.1103/PhysRevB.88.214202 P.Kozelj S.Jazbec S.Vrtnik A.Jelen J.Dolinsek M.Jagodic Z.Jaglicic P.Boulet M. C.de Weerd J.Ledieu J. M.Dubois V.Fournee article ISI:000328025500002 Hydrogen-induced nanotunnel opening within semiconductor subsurface NATURE COMMUNICATIONS 2013 4 Département P2M : Surfaces et Spectroscopies 2041-1723 10.1038/ncomms3800 PatrickSoukiassian ErichWimmer EdvigeCelasco ClaudiaGiallombardo SimonBonanni LucaVattuone LetiziaSavio AntonioTejeda MathieuSilly MarieD'angelo FaustoSirotti MarioRocca article ISI:000318556100019 Identification of LiNbO3, LiNb3O8 and Li3NbO4 phases in thin films synthesized with different deposition techniques by means of XRD and Raman spectroscopy JOURNAL OF PHYSICS-CONDENSED MATTER 2013 25 Centre de Compétences : X-Gamma rayons X et spectroscopie 0953-8984 10.1088/0953-8984/25/20/205901 AusrineBartasyte ValentinaPlausinaitiene AdulfasAbrutis SandraStanionyte SamuelMargueron PascalBoulet T.Kobata YoshiakiUesu JeromeGleize article 201-3793 Impact of plasma transport and turbulence on particle fuelling Journal of Nuclear Materials 2013 438 S154 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/jnucmat.2013.01.023 P.Tamain G.Bonhomme F.Brochard F.Clairet J.Gunn P.Hennequin G.Hornung L.Vermare Ph.Ghendrih article 201-2769 Impacts created on various materials by micro-discharges in heptane: influence of the dissipated charge Journal of Applied Physics 2013 113 043301 Modes of energy dissipation in impacts made on various materials (Al, Cu, Fe, and Si) by discharges in heptane are investigated for micro-gap conditions. Bulk metals and thin films of 300 nm in thickness deposited on silicon wafers are used as samples. Positive high voltage pulses with nanosecond rise times make it possible to isolate a single discharge and to study the way the charge delivered by the power supply is transferred to the larger electrode (the sample) in a pin-to-plate configuration. The diameter of the impacts created by the plasma varies linearly versus the charge raised at a power close to 0.5. However, the exact value of the power depends on the material. We also show how the impact morphologies change with the applied charge. At high charges, the diameters of impacts on thin films behave as those made on silicon. At low charges, they behave as the bulk material. Finally, we show that the energy dissipated in impacts is below a few percent. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1063/1.4780786 A.Hamdan J.-N.Audinot S.Migot-Choux C. Noël G.Henrion T.Belmonte article ISI:000314724500014 Impacts created on various materials by micro-discharges in heptane: Influence of the dissipated charge JOURNAL OF APPLIED PHYSICS 2013 113 4 Modes of energy dissipation in impacts made on various materials (Al, Cu, Fe, and Si) by discharges in heptane are investigated for micro-gap conditions. Bulk metals and thin films of 300 nm in thickness deposited on silicon wafers are used as samples. Positive high voltage pulses with nanosecond rise times make it possible to isolate a single discharge and to study the way the charge delivered by the power supply is transferred to the larger electrode (the sample) in a pin-to-plate configuration. The diameter of the impacts created by the plasma varies linearly versus the charge raised at a power close to 0.5. However, the exact value of the power depends on the material. We also show how the impact morphologies change with the applied charge. At high charges, the diameters of impacts on thin films behave as those made on silicon. At low charges, they behave as the bulk material. Finally, we show that the energy dissipated in impacts is below a few percent. (C) 2013 American Institute of Physics. <prt>[</prt>http://dx.doi.org/10.1063/1.4780786] Belmonte, T (Reprint Author), Univ Lorraine, Inst Jean Lamour, CNRS, UMR 7198, F-54042 Nancy, France. Hamdan, A.; Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., Univ Lorraine, Inst Jean Lamour, CNRS, UMR 7198, F-54042 Nancy, France. Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., Inst Jean Lamour, CNRS, UMR 7198, F-54042 Nancy, France. Centre de Compétences : ERMIONE informatique et calcul AMER INST PHYSICS
CIRCULATION &amp; FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA
Article English 0021-8979 10.1063/1.4780786 A.Hamdan C.Noel F.Kosior G.Henrion T.Belmonte
article Aubert2013 In situ high-temperature characterization of AlN-based surface acoustic wave devices Journal of Applied Physics 2013 114 1 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84880914482&amp;partnerID=40&amp;md5=b8fcd928a8a0a506d9921cf3cdf41e1f T.Aubert J.Bardong O.Legrani O.Elmazria M.Badreddine Assouar G.Bruckner A.Talbi article 201-3910 Influence of Sn content on properties of ZnO:SnO2 thin films deposited by ultrasonic spray pyrolysis Materials Science in Semiconductor Processing 2013 16 2021-2027 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.mssp.2013.07.023 F.Ynineb A.Hafdallah M.S.Aida N.Attaf J.Bougdira H.Rinnert S.Rahmane article Devynck:2013 Influence of the impact angle and the direction against gravity on heat transfer during the cooling of a cylinder by a free planar subcooled impinging jet. Key Engineering Materials 2013 554--557 1530--1538 Département SI2M : Microstructures et Contraintes 10.4028/www.scientific.net/KEM.554-557.1530 S.Devynck M.Gradeck J.P.Bellot S.Denis G.Maigrat M.Varlez T.Benard article ISI:000325367100003 Interaction of Discharges in Heptane with Silicon Covered by a Carpet of Carbon Nanotubes ADVANCED ENGINEERING MATERIALS 2013 15 10 885-892 Discharges in heptane in pin-to-plate configuration are produced between a platinum wire and a (100)-oriented silicon wafer coated by a carbon nanotube (CNT) carpet. This carpet is used to simulate the behavior of a nanostructured surface in electro-discharge machining (EDM) where small protrusions on the surface could play a similar role. CNTs behave like simple electrical conductors between the discharge and the silicon wafer. They act as if they would focus the current on smaller areas. The average diameter of impacts is about five times smaller if the silicon wafer is coated by a CNT carpet. The underlying silicon surface is heated by the plasma and melts, forming a central spot surrounded by a serrated trailing edge. The current density being about one order of magnitude larger when a CNT carpet is present, the induced magnetic field stirs the molten silicon, creating serrations all around the impact. Hot nanoparticles of carbon coming from the plasma fall and roll randomly on the silicon surface where they create wavy micro-channels. Nanowires that are detached from the surface are covered by nanoparticles of platinum in the plasma and embedded within an amorphous carbon layer deposited on the nanotube. However, these effects can only be observed if the current density is high enough (&gt;approximate to 10A mu m(-2) depending on the material) like in micro-EDM but not in nano-EDM. Hamdan, A (Reprint Author), Univ Lorraine, Inst Jean Lamour, CNRS, UMR 7198, F-54042 Nancy, France. Hamdan, Ahmad; Migot-Choux, Sylvie; Noel, Cedric; Kosior, Francis; Henrion, Gerard; Belmonte, Thierry, Univ Lorraine, Inst Jean Lamour, CNRS, UMR 7198, F-54042 Nancy, France. Audinot, Jean-Nicolas, Ctr Rech Publ Gabriel Lippmann, SAM Dept, L-4422 Belvaux, Luxembourg. Centre de Compétences : ERMIONE informatique et calcul WILEY-V C H VERLAG GMBH
BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY
Article English 1438-1656 10.1002/adem.201300106 AhmadHamdan Jean-NicolasAudinot SylvieMigot-Choux CedricNoel FrancisKosior GerardHenrion ThierryBelmonte
article 201-3777 Interaction of Discharges in Heptane with Silicon Covered by a Carpet of Carbon Nanotubes, Advanced Engineering Materials 2013 15 885-892 Discharges in heptane in pin-to-plate configuration are produced between a platinum wire and a (100)-oriented silicon wafer coated by a carbon nanotube (CNT) carpet. This carpet is used to simulate the behavior of a nanostructured surface in electro-discharge machining (EDM) where small protrusions on the surface could play a similar role. CNTs behave like simple electrical conductors between the discharge and the silicon wafer. They act as if they would focus the current on smaller areas. The average diameter of impacts is about five times smaller if the silicon wafer is coated by a CNT carpet. The underlying silicon surface is heated by the plasma and melts, forming a central spot surrounded by a serrated trailing edge. The current density being about one order of magnitude larger when a CNT carpet is present, the induced magnetic field stirs the molten silicon, creating serrations all around the impact. Hot nanoparticles of carbon coming from the plasma fall and roll randomly on the silicon surface where they create wavy micro-channels. Nanowires that are detached from the surface are covered by nanoparticles of platinum in the plasma and embedded within an amorphous carbon layer deposited on the nanotube. However, these effects can only be observed if the current density is high enough (&gt;approximate to 10A mu m(-2) depending on the material) like in micro-EDM but not in nano-EDM. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1002/adem.201300106 A.Hamdan J.-N.Audinot S.Migot-Choux C.Noel F.Kosior G.Henrion T.Belmonte article 201-3778 Interaction of micro-discharges in heptane with metallic multi-layers Applied Surface Science 2013 274 378-391 Interaction of discharges in heptane with magnetron-sputtered thin films made of aluminum, copper or iron is studied in a pin-to-plate configuration. The behavior of discharges on thin films can be used to better understand the interaction of discharges with given surfaces and it might also improve the reproducibility of the impacts in order to better control their shape. Single layers and bilayers of metals are characterized after impact by SEM, AFM, micro-EDX and nano-SIMS analyses. Discharges last typically for a few hundreds of nanoseconds and dissipated energies range between 1 and 100 mJ. We show that at low impact energy, copper and aluminum are heated and stretched by surface stress. At intermediate energy, melting occurs, leading to the synthesis of external beads by Marangoni's convection. At high energy, the shape of the impact is defined by the pressure release when the discharge stops. When iron is deposited onto silicon, dewetting is an important mechanism. The columnar structure of the deposit may have two distinct roles. On the one hand, gases trapped in intercolumnar boundaries can produce tiny holes. On the other hand, the shock wave can abrade the outermost and less cohesive part of the film if it is made of columns separated by large porosities. (C) 2013 Elsevier B.V. All rights reserved. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.apsusc.2013.03.074 A.Hamdan J.-N.Audinot C.Noel F.Kosior G.Henrion T.Belmonte article ISI:000318598600058 Interaction of micro-discharges in heptane with metallic multi-layers APPLIED SURFACE SCIENCE 2013 274 378-391 Interaction of discharges in heptane with magnetron-sputtered thin films made of aluminum, copper or iron is studied in a pin-to-plate configuration. The behavior of discharges on thin films can be used to better understand the interaction of discharges with given surfaces and it might also improve the reproducibility of the impacts in order to better control their shape. Single layers and bilayers of metals are characterized after impact by SEM, AFM, micro-EDX and nano-SIMS analyses. Discharges last typically for a few hundreds of nanoseconds and dissipated energies range between 1 and 100 mJ. We show that at low impact energy, copper and aluminum are heated and stretched by surface stress. At intermediate energy, melting occurs, leading to the synthesis of external beads by Marangoni's convection. At high energy, the shape of the impact is defined by the pressure release when the discharge stops. When iron is deposited onto silicon, dewetting is an important mechanism. The columnar structure of the deposit may have two distinct roles. On the one hand, gases trapped in intercolumnar boundaries can produce tiny holes. On the other hand, the shock wave can abrade the outermost and less cohesive part of the film if it is made of columns separated by large porosities. (C) 2013 Elsevier B.V. All rights reserved. Belmonte, T (Reprint Author), Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, F-54011 Nancy, France. Hamdan, A.; Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., Univ Lorraine, Inst Jean Lamour, UMR CNRS 7198, F-54011 Nancy, France. Audinot, J. -N., Ctr Rech Publ Gabriel Lippmann, SAM Dept, L-4422 Belvaux, Luxembourg. Noel, C.; Kosior, F.; Henrion, G.; Belmonte, T., CNRS, Inst Jean Lamour, UMR CNRS 7198, F-54011 Nancy, France. Centre de Compétences : ERMIONE informatique et calcul Microplasma; Plasma in liquids; Plasma-surface interaction; Thin films ELSEVIER SCIENCE BV
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Article English 0169-4332 10.1016/j.apsusc.2013.03.074 A.Hamdan J. -N.Audinot C.Noel F.Kosior G.Henrion T.Belmonte
article 201-3852 Interaction of streamer in heptane with metallic multi-layers Applied Surface Science 2013 274 378-391 Interaction of discharges in heptane with magnetron-sputtered thin films made of aluminum, copper or iron is studied in a pin-to-plate configuration. The behavior of discharges on thin films can be used to better understand the interaction of discharges with given surfaces and it might also improve the reproducibility of the impacts in order to better control their shape. Single layers and bilayers of metals are characterized after impact by SEM, AFM, micro-EDX and nano-SIMS analyses. Discharges last typically for a few hundreds of nanoseconds and dissipated energies range between 1 and 100 mJ. We show that at low impact energy, copper and aluminum are heated and stretched by surface stress. At intermediate energy, melting occurs, leading to the synthesis of external beads by Marangoniâ??s convection. At high energy, the shape of the impact is defined by the pressure release when the discharge stops. When iron is deposited onto silicon, dewetting is an important mechanism. The columnar structure of the deposit may have two distinct roles. On the one hand, gases trapped in intercolumnar boundaries can produce tiny holes. On the other hand, the shock wave can abrade the outermost and less cohesive part of the film if it is made of columns separated by large porosities. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.apsusc.2013.03.074 A.Hamdan J.-N.Audinot C.Noel F.Kosior G.Henrion T.Belmonte article ISI:000329891400094 Isothermal alpha `' formation in beta metastable titanium alloys JOURNAL OF ALLOYS AND COMPOUNDS 2013 577 S439-S443 Centre de Compétences : X-Gamma rayons X et spectroscopie 0925-8388 10.1016/j.jallcom.2012.02.046 E.Aeby-Gautier A.Settefrati F.Bruneseaux B.Appolaire B.Denand M.Dehmas G.Geandier P.Boulet article Aeby-Gautier:2013 Isothermal alpha&quot; formation in beta metastable titanium alloys Journal of Alloys and Compounds 2013 5775 439-443 Département SI2M : Microstructures et Contraintes 10.1016/j.jallcom.2012.02.046 E.Aeby-Gautier A.Settefrati F.Bruneseaux B.Appolaire B.Denand M.Dehmas G.Geandier P.Boulet article Briones2013 Large area patterned magnetic films by depositing cobalt layers on nano-wrinkled polydimethylsiloxane templates Applied Physics Letters 2013 103 7 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84882394652&amp;partnerID=40&amp;md5=12fb71b0f8a8a9bb4ea68d662d561136 J.Briones P.Toro A.Encinas L.Caballero J.C.Denardin F.Melo E.Cerda S.Robert D.Lacour F.Montaigne article ISI:000323769000050 Large area patterned magnetic films by depositing cobalt layers on nano-wrinkled polydimethylsiloxane templates APPLIED PHYSICS LETTERS 2013 103 Centre de Compétences : X-Gamma rayons X et spectroscopie 0003-6951 10.1063/1.4818677 J.Briones P.Toro A.Encinas L.Caballero J. C.Denardin F.Melo E.Cerda S.Robert D.Lacour F.Montaigne article ISI:000317390000004 Magnetic and electronic properties of NpCo2: Evidence for long-range magnetic order PHYSICAL REVIEW B 2013 87 Centre de Compétences : X-Gamma rayons X et spectroscopie 1098-0121 10.1103/PhysRevB.87.134410 J. P.Sanchez J. -C.Griveau P.Javorsky E.Colineau R.Eloirdi P.Boulet J.Rebizant F.Wastin A. B.Shick R.Caciuffo article Bersweiler2013 Magnetic control of the zero-magnetization ferromagnet Sm1 -xGdxAl2 Physical Review B - Condensed Matter and Materials Physics 2013 88 5 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84883136566&amp;partnerID=40&amp;md5=1cdf934b8668a62acb871159cc91049b M.Bersweiler K.Dumesnil F.Wilhelm A.Rogalev article 201-3912 Microstructure and opto-electrical properties of SnO 2: In 2 O 3 alloys thin films prepared by ultrasonic spray International Journal of Nanoparticles 2013 6 252-263 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1504/IJNP.2013.055001 F.Ynineb A.Hafdallah N.Attaf M.S.Aida J.Bougdira H.Rinnert article CP2S011 Mo6S8 Electrochemical Transfer Junction for Selective Extraction of Co2+-Ions from Mixed Solutions with Ni2+-ions Journal of Electrochemical Society 2013 160 3 A420-A425 Département CP2S : Chimie et électrochimie des matériaux E.Guyot S.Seghir J.M.Lecuire C.Boulanger M.D.Levi Y.Shilina V.Dargel D.Aurbach article Kim20136930 Nanoparticle-free magnetic mesoporous silica with magneto-responsive surfactants Journal of Materials Chemistry C 2013 1 42 6930-6934 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84885439704&amp;partnerID=40&amp;md5=104b2a4077fe26d92d2e9e36c86936a6 S.Kim C.Bellouard A.Pasc E.Lamouroux J.-L.Blin C.Carteret Y.Fort M.Emo P.Durand M.-J.STEBE article ISI:000319568800008 Near-room temperature single-domain epitaxy of reactively sputtered ZnO films JOURNAL OF PHYSICS D-APPLIED PHYSICS 2013 46 Centre de Compétences : X-Gamma rayons X et spectroscopie 0022-3727 10.1088/0022-3727/46/23/235107 W.Chamorro D.Horwat P.Pigeat P.Miska S.Migot F.SOLDERA P.Boulet F.MUECKLICH article bonina_nouveaux_2013 Nouveaux matériaux composites à base d’agarose pour le brasage de pièces en cuivre Revue de Métallurgie 2013 110 04 297--305 Centre de Compétences : Matériaux et Procédés additifs DBonina SKenzari article 201-4442 Overview of ASDEX Upgrade results Nuclear Fusion 2013 53 104003 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1088/0029-5515/53/10/104003 U.Stroth J.Adamek L.Aho-Mantila S.Akaslompolo C.Amdor C.Angioni M.Balden S.Bardin L.Barrera-Orte K.Behler E.Belonohy A.Bergmann M.Bernert R.Bilato G.Birkenmeier V.Bobkov J.Boom C.Bottereau A.Bottino F.Braun S.Brezinsek F.Brochard M.Brudgam A.Buhler A.Burckhart F.J.Casson A.Chankin I.Chapman F.Clairet I.G.J.Classen J.W.Coenen G.D.Conway D.P.Coster D.Curran F.Da Silva P.De Marne R.D’inca D.Douai R.Drube M.Dunne R.Dux T.Eich H.Eixenberger N.Endstrasser K.Engelhardt B.Esposito E.Fable R.Fischer H.Funfgelder J.C.Fuchs K.Gal M.G. Munoz B.Geiger L.Giannone T.Gorler S.Da Graca H.Greuner O.Gruber A.Gude L.Guimarais S.Gunter G.Haas A.H.Hakola D.Hangan T.Happel T.Hartl T.Hauff B.Heinemann A.Herrmann J.Hobirk H.Hohnle M.Holzl C.Hopf A.Houben V.Igochine C.Ionita A.Janzer F.Jenko M.Kantor C.-P.Kasemann A.Kallenbach S.Kalvin M.Kantor A.Kappatou O.Kardaun W.Kasparek M.Kaufmann A.Kirk H.-J.Klingshirn M.Kocan G.Kocsis C.Konz R.Koslowski K.Krieger M.Kubic T.Kurki-Suonio B.Kurzan K.Lackner P.T.Lang P.Lauber others article Legrani2013487 Packageless AlN/ZnO/Si structure for SAW devices applications IEEE Sensors Journal 2013 13 2 487-491 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84872292161&amp;partnerID=40&amp;md5=7c3de04a0ea83447147f2d9ecd34777c O.Legrani O.Elmazria S.Zhgoon P.Pigeat A.Bartasyte article 201-3779 Plasma-surface interaction in heptane Journal of Applied Physics 2013 113 213303 The main processes related to discharges between pin and plate electrodes in hydrocarbon liquid (heptane) are modelled for micro-gap (from 10 to 100 mu m) conditions. When a plasma channel hits the surface, a micro-crater is created. The different phenomena controlling the geometry (shape and dimension) of a single crater are described and included in a theoretical model developed for the specific case of pure aluminium. The influence of the most important parameters affecting the geometry of the crater is discussed. Among them, one finds the pressure exerted by the plasma on the liquid metal. It is found that the distribution of the pressure applied on the liquid pool changes significantly the way the plasma shapes the pool. It is assumed that at high charges, the pressure profile is tilted from the channel axis, leading to the formation of a central protrusion. On the other hand, we demonstrate that Thomson-Marangoni forces play an important role for crater diameters smaller than 5 mu m. Then, the choice of the first derivative of the surface tension with respect to the temperature is a key factor. This effect is strongly related to the way convection displaces matter in the liquid pool. Finally, the quenching step is sufficiently fast to freeze the liquid shape as soon as the plasma vanishes. (C) 2013 AIP Publishing LLC. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1063/1.4809766 A.Hamdan F.Kosior C.Noel G.Henrion J.-N.Audinot T.Gries T.Belmonte article ISI:000320674500016 Plasma-surface interaction in heptane JOURNAL OF APPLIED PHYSICS 2013 113 21 The main processes related to discharges between pin and plate electrodes in hydrocarbon liquid (heptane) are modelled for micro-gap (from 10 to 100 mu m) conditions. When a plasma channel hits the surface, a micro-crater is created. The different phenomena controlling the geometry (shape and dimension) of a single crater are described and included in a theoretical model developed for the specific case of pure aluminium. The influence of the most important parameters affecting the geometry of the crater is discussed. Among them, one finds the pressure exerted by the plasma on the liquid metal. It is found that the distribution of the pressure applied on the liquid pool changes significantly the way the plasma shapes the pool. It is assumed that at high charges, the pressure profile is tilted from the channel axis, leading to the formation of a central protrusion. On the other hand, we demonstrate that Thomson-Marangoni forces play an important role for crater diameters smaller than 5 mu m. Then, the choice of the first derivative of the surface tension with respect to the temperature is a key factor. This effect is strongly related to the way convection displaces matter in the liquid pool. Finally, the quenching step is sufficiently fast to freeze the liquid shape as soon as the plasma vanishes. (C) 2013 AIP Publishing LLC. Belmonte, T (Reprint Author), Univ Lorraine, CNRS, Dept CP2S, Inst Jean Lamour, Parc Saurupt,CS 50840, F-54011 Nancy, France. Hamdan, A.; Kosior, F.; Noel, C.; Henrion, G.; Gries, T.; Belmonte, T., Univ Lorraine, CNRS, Dept CP2S, Inst Jean Lamour, F-54011 Nancy, France. Audinot, J-N, Ctr Rech Publ Gabriel Lippmann, SAM Dept, L-4422 Belvaux, Luxembourg. Centre de Compétences : ERMIONE informatique et calcul AMER INST PHYSICS
CIRCULATION &amp; FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA
Article English 10.1063/1.4809766 A.Hamdan F.Kosior C.Noel G.Henrion J-NAudinot T.Gries T.Belmonte
article CP2S009 Psychotria douarrei and Geissois pruinosa, novel resources for the plant-based catalytic chemistry RSC Advances 2013 3 44 22340-22345 Psychotria douarrei and Geissois pruinosa are known as a hypernickelophore plants. The study of their chemical characteristics was revisited to demonstrate a novel potential of this natural resource for Green Chemistry. P. douarrei showed a unique composition, which led to a novel concept of plant-based catalytic chemistry. The supported Biginelli reaction illustrated an interest of this concept for green organic synthesis. Département CP2S : Chimie et électrochimie des matériaux ClaireGrison VincentEscande EddyPetit LaetitiaGaroux ClotildeBoulanger ClaudeGrison article 201-4180 Real-time Raman spectroscopy measurements to study the uniaxial tension of isotactic polypropylene : a global overview of microstructural deformation mechanisms Journal of Raman Spectroscopy 2013 44 5 776-784 Micro-Raman spectroscopy was used to investigate the main deformation micromechanisms of isotactic polypropylene uniaxially stretched at constant temperature (T=30 degrees C) under a constant true strain rate (epsilon.zz = 5.103s1). To accurate measurements namely to be free of the recovering phenomenon which causes in most of the cases interference during post-mortem analysis, we introduced a new experimental setup combining a Raman spectrometer with a tensile machine piloted by the VideoTraction system. Microstructure is described by essential parameters such as the crystallinity index, the macromolecular orientation both in the crystalline and the amorphous phase, and distribution of the internal stress at the chemical bonds scale. For each, a well-tried Raman spectral criterion was used. Cross-checking of these results, obtained with a minimum of tensile tests, allows a more complete understanding of the deformation micromechanisms of semi-crystalline polymer. Copyright (c) 2013 John Wiley &amp; Sons, Ltd. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1002/jrs.4244 J.Martin M.Ponçot J.M. Hiver P.Bourson A.Dahoun article 201-3854 Retrieving particle size and density from extinction measurement in dusty plasma : Monte Carlo inversion and Ray-tracing comparison Journal of Quantitative Spectroscopy and Radiative Transfer 2013 128 18-26 Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.jqsrt.2012.07.010 S.Dap D.Lacroix R.Hugon J.Bougdira. article ISI:000328678600008 Reversible charge storage in a single silicon atom PHYSICAL REVIEW B 2013 88 24 Département P2M : Surfaces et Spectroscopies 1098-0121 10.1103/PhysRevB.88.241406 AmandineBellec LaurentChaput GeraldDujardin DamienRiedel LouiseStauffer PhilippeSonnet article López-Flores2013 Role of critical spin fluctuations in ultrafast demagnetization of transition-metal rare-earth alloys Physical Review B - Condensed Matter and Materials Physics 2013 87 21 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84878981460&amp;partnerID=40&amp;md5=4d723b8565d89e34e86269fe178fa800 V.López-Flores N.Bergeard V.Halté C.Stamm N.Pontius M.Hehn E.Otero E.Beaurepaire C.Boeglin article Mercier2013790 Selective removal of metal impurities from single walled carbon nanotube samples New Journal of Chemistry 2013 37 3 790-795 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84874091228&amp;partnerID=40&amp;md5=cb042fda4868e8defce23d523873e3b1 G.Mercier C.Herold J.-F.Marêché S.Cahen J.Gleize J.Ghanbaja G.Lamura C.Bellouard B.Vigolo article Cascales20134347 Shot noise in epitaxial double-barrier magnetic tunnel junctions IEEE Transactions on Magnetics 2013 49 7 4347-4350 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84880842943&amp;partnerID=40&amp;md5=64dd058a9b4a18443d9d19d03bcc9a54 J.P.Cascales L.Martin A.Dulluard M.Hehn C.Tiusan T.Szczepa?ski V.Dugaev J.Barnaš F.G.Aliev article Cascales20134347 Shot noise in epitaxial double-barrier magnetic tunnel junctions IEEE Transactions on Magnetics 2013 49 7 4347-4350 Centre de Compétences : MiNaLor micro et nanotechnologies http://www.scopus.com/inward/record.url?eid=2-s2.0-84880842943&amp;partnerID=40&amp;md5=64dd058a9b4a18443d9d19d03bcc9a54 J.P.Cascales L.Martin A.Dulluard M.Hehn C.Tiusan T.Szczepa?ski V.Dugaev J.Barna? F.G.Aliev article ISI:000313651600047 Structural, tribological and resistivity studies of Ga substituted (Al71-xGax) Pd21Mn8 icosahedral and other intermetallic phases JOURNAL OF ALLOYS AND COMPOUNDS 2013 551 274-278 Département CP2S : Métallurgie et Surfaces 0925-8388 10.1016/j.jallcom.2012.09.130 MurtazaBohra M. C.de Weerd VincentFournee R. K.Mandal N. K.Mukhopadhyay RatnamalaChatterjee G. V. S.Sastry article ISI:000325992600006 STUDY OF ELECTRON, PHONON AND CRYSTAL STABILITY VERSUS THERMOELECTRIC PROPERTIES IN Mg2X (X = Si, Sn) COMPOUNDS AND THEIR ALLOYS FUNCTIONAL MATERIALS LETTERS 2013 6 5 Département P2M : Surfaces et Spectroscopies 1793-6047 10.1142/S1793604713400055 J.Bourgeois J.TOBOLA B.Wiendlocha L.Chaput P.Zwolenski D.Berthebaud F.Gascoin Q.Recour H.SCHERRER article 201-3853 Study of RONS-bacteria interaction with mass spectrometry nanoimaging Proceedings of the National Academy of Sciences of the United States of America 2013 soumis Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS D.Duday F.Clement E.Lecoq C.Penny J.-N.Audinot T.Belmonte K.Kutasi H.-M.Cauchie P.Choquet article CP2S001 Study of the potential driven changes in a collagen film self-assembled on a polycrystalline gold electrode surface Journal of Electroanalytical Chemistry 2013 706 140-148 Abstract The influence of the potential applied to the polycrystalline gold electrode on the adsorption state and structure of collagen molecules were studied by means of electrochemistry, in situ ellipsometry and in situ polarization modulation infrared reflection–absorption spectroscopy. At the macroscopic level, potential and the corresponding charge accumulated on the gold electrode determine the adsorption process of the collagen film on the Au electrode surface. The protein film is stable on the electrode surface at potentials close to the potential of zero charge. The protein film sustains a large negative potential drop (??M|S ? ?0.5 V) whereas it is unstable at a small positive potential drop (??M|S ? 0.1 V) across the film. Positive net charge accumulated on the Au surface causes electrostatic repulsions of collagen molecules bearing a positive net charge. Loosening of water and destabilization of the protein film reflect repulsions between the Au electrode and the collagen molecules. In contrast, at charge densities between ?8 &lt; ?M &lt; ?20 ?C cm?2 electrostatic attractions between the electrode surface and the protein molecule appear. A stable, well hydrated collagen film is formed on the Au surface. Higher negative charges accumulated on the electrode surface lead to swelling on the protein film by water and lead to the desorption of the protein film from the Au surface. In situ spectroelectrochemical studies show that at the molecular level neither the secondary structure nor the orientation of collagen molecules are affected by electrical potentials. Independently of the applied potential and electric fields acting on the film the collagen molecule maintains its native structure. Collagen molecules adsorbed on the Au surface form a heterogeneous film with well-defined structure and unusual stability at the molecular level. Département CP2S : Chimie et électrochimie des matériaux Collagen molecule Self-assembly Au electrode In situ ellipsometry Capacitance Polarization modulation infrared reflection–absorption spectroscopy (PM IRRAS) MichaelAhlers NicolasStein LaurentBroch IzabellaBrand article ISI:000321307000037 Synthesis and electronic structure of a two dimensional pi-conjugated polythiophene CHEMICAL SCIENCE 2013 4 8 3263-3268 Département P2M : Surfaces et Spectroscopies 2041-6520 10.1039/c3sc50800e LuisCardenas RicoGutzler JoshLipton-Duffin ChaoyingFu Jaclyn L.Brusso Laurentiu E.Dinca MartinVondracak YannickFagot-Revurat DanielMalterre FedericoRosei Dmitrii F.Perepichka article 201-3780 Synthesis of platinum embedded in amorphous carbon by micro-gap discharge in heptane Materials Chemistry and Physics 2013 142 199-206 Micro-gap discharges created in heptane between two platinum pin-electrodes produce platinum particles embedded in an amorphous carbon matrix which exhibits a short-range order. The platinum particles can be sorted by size. The largest ones (&gt;100 nm in diameter) are created by emission of droplets from the liquid pool formed when the discharge hits the electrode surface. They are submitted to high stress levels by fast thermal quenching. The smallest ones (&lt;5 nm) are synthesized in the plasma. Nanoparticles with diameters ranging from 10 to 20 nm have structure defects and are synthesized in post-discharge where huge temperature gradients exist. The short-range order observed in carbon extends typically over 3 nm, and it is observed by high-resolution transmission electron microscopy. This ordered structure of carbon (and a fortiori sp(3) bonds which are identified by FTIR analyses) is clearly visible around the smallest nanoparticles and it is likely formed at the same location, i.e. in the plasma. (C) 2013 Elsevier B.V. All rights reserved. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.matchemphys.2013.07.006 A.Hamdan C.Noel J.Ghanbaja S.Migot-Choux T.Belmonte article Gopman2013 Temperature dependence of the switching field in all-perpendicular spin-valve nanopillars Physical Review B - Condensed Matter and Materials Physics 2013 88 10 Département P2M : Nanomagnétisme et Electronique de Spin http://www.scopus.com/inward/record.url?eid=2-s2.0-84884843823&amp;partnerID=40&amp;md5=c527e95f973a1a1420cf81d5e2507f35 D.B.Gopman D.Bedau G.Wolf S.Mangin E.E.Fullerton J.A.Katine A.D.Kent article ISI:000314881900009 The 2 root 3 x 2 root 3R30 surface reconstruction of alkali/Si(111):B semiconducting surfaces APPLIED SURFACE SCIENCE 2013 267 35-39 Département P2M : Surfaces et Spectroscopies 0169-4332 10.1016/j.apsusc.2012.05.062 C.Tournier-Colletta L.Chaput A.Tejeda L. A.Cardenas B.Kierren D.Malterre Y.Fagot-Revurat P.Le Fèvre F.Bertran A.Taleb-Ibrahimi article 201-3911 The effect of a dust size distribution on electrostatic sheaths in unmagnetized dusty plasmas Physics of Plasmas 2013 20 043508, In this work, the structure of plasma sheaths in presence of dust particles with different sizes is investigated numerically in a multifluid framework, where the dust size distribution is modeled by Gauss' law. For this, we have established a 1D, stationary, unmagnetized, and weakly collisional electronegative dusty plasma sheath model. The electrons and negative ions are considered in a local thermodynamic equilibrium, therefore, described by a Boltzmann distribution. On the other hand, positive ions and dust grains are described by fluid equations. The charging process is described by the orbit motion limited model. It is shown that taking into account dust grains with different sizes reduces considerably the sheath thickness. The behavior of dust surface potential is not affected, but the dust charge number is reduced, as well as the electrostatic force. It results in a decrease of layered structure. The presence of negative ions makes the structure of the electrostatic potential more oscillatory. The other physical parameters are also analyzed and discussed. (C) 2013 American Institute of Physics. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org.bases-doc.univ-lorraine.fr/10.1063/1.4799732 D.Benlemdjaldi A.Tahraoui R.Hugon J.Bougdira article 201-3786 The effect of noble gas bombarding on nitrogen diffusion in steel. Materials Chemistry and Physics 2013 143 116-123 The low energy (similar to 50-350 eV) noble gases ion bombardment of the steel surface shows that the pre-treatments increase nitrogen diffusion by modifying the outermost structure of the material. The surface microstructure and morphology of the studied samples were characterized by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The crystalline and chemical structures in the outermost layers of the surface were analyzed by grazing angle X-ray diffraction (GAXRD) and photoemission electron spectroscopy (XPS). Temperature effusion studies of the implanted ions are used to elucidate the noble gases site localization in the network. The local compressive stress induced by the nearby iron atoms on the core level electron wave functions of the trapped noble gases are studied by photoemission electron spectroscopy (XPS) and interpreted considering a simple mechanical model. Nano-hardness measurements show the dependence of the material elastic constant on the energy of the implanted noble gases. Although the ion implantation range is about few nanometers, the atomic attrition effect is larger enough to modify the material structure in the range of micrometers. Two material stress zones were detected where the outermost layers shows compressive stress and the underneath layers shows tensile stress. The implanted noble gases can be easily removed by heating. A diffusion model for polycrystalline-phase systems is used in order to discuss the influence of the atomic attrition on the N diffusion coefficient. The concomitant effect of grain refining, stress, and surface texture on the enhancing nitrogen diffusion effect is discussed. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1016/j.matchemphys.2013.08.027 E.A.Ochoa R.Droppa R.L.O.Basso M.Morales S.Cucatti L.F.Zagonel T.Czerwiec M.C.Dos Santos C.A.Figueroa F.Alvarez article ISI:000321687800002 The Intermetallic Compound ZnPd and Its Role in Methanol Steam Reforming CATALYSIS REVIEWS-SCIENCE AND ENGINEERING 2013 55 3 289-367 Département CP2S : Métallurgie et Surfaces 0161-4940 10.1080/01614940.2013.796192 M.Armbruester M.Behrens K.Foettinger M.Friedrich E.Gaudry S. K.Matam H. R.SHARMA article 201-3772 Ti-Ar scattering cross sections by direct comparison of Monte Carlo simulations and laser-induced fluorescence spectroscopy in magnetron discharges. Journal of Physics D: Applied Physics 2013 46 175201 A 3D Monte Carlo code (OMEGA) was developed to simulate the transport of sputtered atoms in a magnetron discharge operating in direct current mode. Collisions between the sputtered Ti atoms and the neutral process gas atoms (Ar) were modelled. Spatially resolved simulated velocity distributions of the sputtered particles parallel as well as perpendicular to the cathode surface for different operating pressures were recorded and benchmarked against experimentally obtained profiles using laser-induced fluorescence. New differential (angular and energy-dependent) cross sections for Ti-Ar elastic collisions were thereby obtained, which resulted in good agreement between modelled and experimental results. The differences with respect to commonly used extrapolated Ar-Ar cross sections to describe the Ti-Ar interaction are highlighted and discussed. Département CP2S : Expériences et Simulations des Plasmas Réactifs - Interaction plasma-surface et Traitement des Surfaces ESPRITS http://dx.doi.org/10.1088/0022-3727/46/17/175201 D.Lundin C.Vitelaru DePoucques L N.Brenning T.Minea. article ISI:000314823600005 Understanding the insulating nature of alkali-metal/Si(111):B interfaces JOURNAL OF PHYSICS-CONDENSED MATTER 2013 25 9 Département P2M : Surfaces et Spectroscopies 0953-8984 10.1088/0953-8984/25/9/094004 Y.Fagot-Revurat C.Tournier-Colletta L.Chaput A.Tejeda L.Cardenas B.Kierren D.Malterre P.Le Fèvre F.Bertran A.Taleb-Ibrahimi