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--- Timezone: CET
Creation date: 2021-03-04
Creation time: 08-28-02
--- Number of references
15
article
CP2S021
Performances and mechanistic investigations of a triphosphine trioxide/ionic liquid system for rare earth extraction
Dalton Transactions
2016
45
Copyright (C) 2016 American Chemical Society (ACS). All Rights Reserved.
1259-1268
The extn. of rare earth elements (REEs) from nitric acid soln. with a triphosphine trioxide (TPO) is presented. Performances of such a ligand in ionic liqs. vs. a classical solvent (benzyl ether) are compared. TPO seems to be 10 to 100 times more efficient when it is dissolved in ionic media whatever the concn. of nitric acid involved. Mechanistic investigations reveal that cation exchange classically obsd. in ionic liqs. is not consistent with the exptl. data. Moreover, clear differences in the TPO/Ln complexes between classical and ionic media are highlighted. A stable complex of 1 lanthanide for 3 TPO is formed in an ionic liq. whereas a complex of 1 lanthanide for 6 to 9 TPO is formed in benzyl ether. Back extn. is also studied and good recovery of REEs could be obtained. The TPO/ionic liq. system shows remarkable performances i.e. efficiency and selectivity towards lanthanides in a simulated leaching soln. of a Nd/Fe/B/Dy magnet. [on SciFinder(R)]
Département CP2S : Chimie et électrochimie des matériaux
R.Turgis
G.Arrachart
V.Dubois
S.Dourdain
D.Virieux
S.Michel
S.Legeai
M.Lejeune
M.Draye
S.Pellet-Rostaing
article
CP2S020
Tuning the morphology of Te one-dimensional nanostructures by template-free electrochemical deposition in an ionic liquid
Electrochimica Acta
2016
Abstract Template-free electrodeposition of Te one-dimensional (1 D) nanostructures was carried out from an ionic liquid binary mixture: 1-ethyl-1-octyl-piperidinium bis(trifluoromethylsulfonyl)imide:1-ethyl-1-octyl-piperidinium bromide (EOPipTFSI:EOPipBr 95:5 (mol%)). SAED and XRD analyses confirm the formation of Te 1D nanostructures with a hexagonal single crystalline structure following the [001] direction. A systematic study of the influence of synthesis parameters on the deposits morphology has shown that it is possible to control the shape and the dimensions of the deposited nanostructures. Specifically, the applied potential has a strong influence on the morphology of the deposits. Nanowires or hollow nanostructures can be obtained, depending on mass transport conditions, as confirmed by the use of a soluble anode.
Département CP2S : Chimie et électrochimie des matériaux
Electrodeposition Nanowires Tellurium Ionic liquid Hollow nanostructures
LauraThiebaud
SophieLegeai
NicolasStein
article
CP2S014
Thermal conductivity of Bi2Te3 tilted nanowires, a molecular dynamics study
Applied Physics Letters
2015
106
23
233108
Département CP2S : Chimie et électrochimie des matériaux
molecular dynamics method phonons thermal conductivity bismuth compounds nanowires
ShenLi
LaurentChaput
NicolasStein
CedricFrantz
DavidLacroix
KonstantinosTermentzidis
article
CP2S007
Ecological catalysis and phytoextraction: Symbiosis for future
Applied Catalysis., B
2014
146
279-288
Metallophyte plants derived from phytoextn. are used as starting materials to prep. novel polymetallic catalysts. Polymetallic catalyst activity is used in many Lewis acid catalyzed reactions according to the polymetallic catalyst prepn. The synergetic catalysis of these systems leads to efficient syntheses of complex biomols. such as dihydropyrimidinone, 5'-capped DNA and RNA, and glycosyl aminoacid. These new polymetallic catalysts also bring new possibilities in Green Catalysis, that we named "Ecol. Catalysis". [on SciFinder(R)]
Département CP2S : Chimie et électrochimie des matériaux
VincentEscande
LaetitiaGaroux
ClaireGrison
YannThillier
FrancoiseDebart
Jean-JacquesVasseur
ClothildeBoulanger
ClaudeGrison
article
208-1878
Electrodeposition of bismuth telluride nanowires with controlled composition in polycarbonate membranes
Electrochimica Acta
2012
Département CP2S : Chimie et électrochimie des matériaux
CedricFrantz
NicolasStein
YudongZhang
EmmanuelBouzy
OliverPicht
Maria EugeniaToimil-Molares
ClotildeBoulanger
article
208-1609
Artificially nanostructured n-type SiGe bulk thermoelectrics through plasma enhanced growth of alloy nanoparticles from the gas phase
Journal of Materials Research
2011
26
15
1872-1878
Département CP2S : Chimie et électrochimie des matériaux
N.Stein
N.Petermann
R.Theissmann
G.Schierning
R.Schmechel
H.Wiggers
article
208-1608
Artificially nanostructured n-type SiGe bulk thermoelectrics through plasma enhanced growth of alloy nanoparticles from the gas phase (vol 26, pg 1872, 2011)
Journal of Materials Research
2011
26
18
2459-2459
Département CP2S : Chimie et électrochimie des matériaux
N.Stein
N.Petermann
R.Theissmann
G.Schierning
R.Schmechel
H.Wiggers
article
208-1882
Cyclic-voltammetry study of bismuth telluride electrodeposition in polycarbonate etched ion -track membranes
GSI Scientific Report
2011
PNI-MR-33
401
Département CP2S : Chimie et électrochimie des matériaux
NStein
CBoulanger
CFrantz
OPicht
MToimil-Molares
article
208-1612
From nanoparticles to nanocrystalline bulk: percolation effects in field assisted sintering of silicon nanoparticles
Nanotechnology
2011
22
13
Département CP2S : Chimie et électrochimie des matériaux
D.Schwesig
G.Schierning
R.Theissmann
N.Stein
N.Petermann
H.Wiggers
R.Schmechel
D. E.Wolf
article
208-1606
New insight into indium electrochemistry in a Tf2N-based room-temperature ionic liquid
Electrochimica Acta
2011
58
532-540
Département CP2S : Chimie et électrochimie des matériaux
Y.Traore
S.Legeai
S.Diliberto
G.Arrachart
S.Pellet-Rostaing
M.Draye
article
208-1607
Role of oxygen on microstructure and thermoelectric properties of silicon nanocomposites
Journal of Applied Physics
2011
110
11
Département CP2S : Chimie et électrochimie des matériaux
G.Schierning
R.Theissmann
N.Stein
N.Petermann
A.Becker
M.Engenhorst
V.Kessler
M.Geller
A.Beckel
H.Wiggers
R.Schmechel
article
208-1473
Synthesis, Physicochemical Properties, and Toxicity Data of New Hydrophobic Ionic Liquids Containing Dimethylpyridinium and Trimethylpyridinium Cations
Journal of Chemical and Engineering Data
2010
55
5
1971-1979
Département CP2S : Chimie et électrochimie des matériaux
N.Papaiconomou
J.Estager
Y.Traore
P.Bauduin
C.Bas
S.Legeai
S.Viboud
M.Draye
article
208-1468
Analysis of carrier parameters and bandgap of electroplated Bi2Te3 films by infrared spectroscopic ellipsometry
Physica Status Solidi C - Current Topics in Solid State Physics
2008
5
5
1190-1193
Département CP2S : Chimie et électrochimie des matériaux
A.Zimmer
N.Stein
H.Terryn
L.Johann
C.Boulanger
article
208-1467
Characterizations of bismuth telluride films from Mott-Schottky plot and spectroscopic ellipsometry
Surface and Interface Analysis
2008
40
3-4
593-596
Département CP2S : Chimie et électrochimie des matériaux
A.Zimmer
N.Stein
L.Johann
H.Terryn
C.Boulanger
article
208-1456
Optical and thermoelectric characterizations of electroplated n-Bi-2(Te0.9Se0.1)(3)
Journal of Physics and Chemistry of Solids
2007
68
10
1902-1907
Département CP2S : Chimie et électrochimie des matériaux
A.Zimmer
N.Stein
H.Terryn
C.Boulanger